Condensation of Lactones with Primary Diamines

نویسندگان

چکیده

The condensation of dehydroacetic acid and 4-hydroxy-6-methylpyran-2-one with primary diamine derivatives such as hydrazine, 1,2-diaminoethane 1,6-diaminohexane yielded bispyrone bispyridone has been reported. hydrazine in acetonitrile generated another bispyrazole product but n-butanol, this reaction afforded the bispyridones. structures synthesized bispyrazoles were examined by spectroscopy X-ray diffraction analysis, while those bispyridones established data (NMR, mass). Some new complexes also order to show behaviour ligands suitable crystals for analysis.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

I2-catalyzed oxidative condensation of aldoses with diamines: synthesis of aldo-naphthimidazoles for carbohydrate analysis.

A novel method for the conversion of unprotected and unmodified aldoses to aldo-imidazoles has been developed. Using iodine as a catalyst in acetic acid solution, a series of mono- and oligosaccharides, including those containing carboxyl and acetamido groups, undergo an oxidative condensation reaction with aromatic vicinal diamines at room temperature to give the corresponding aldo-imidazole p...

متن کامل

Multiple deprotonation of primary aromatic diamines by LiAlH4.

Reaction of LiAlH4 with 1,2-phenylenediamine (1H4) in THF results in formation of the metallocyclic amido-/imido complex [{Al(1H2)}2{Al(1H)2}2][Li(THF)2]4 (3), while in the presence of various Lewis base ligands 1,8-diaminonaphthalene (2H4) gives the amido-('ate') complexes [Al(2H2)2](-)[Li(LL')](+) [L = THF, L' = PMDETA (N,N,N',N',N''-pentamethyldiethylenetriamine) (4); L = L' = TMEDA (N,N,N',...

متن کامل

Lactones with a fragrance properties

The various types of lactones have different durability and properties. The most stable among γ-lactones and δ-lactones, which are those containing respectively five or six carbon in the cyclic ring. The lowest durability can be attributed to α-lactones, due to the strong tension torsion and angle of bonds between the atoms forming the ring. Similar tension, to a lesser extent also observed in ...

متن کامل

Bicyclization involving pseudo-intramolecular imination with diamines.

α-Nitro-δ-keto nitriles and α-nitro-δ-keto ester were readily converted to diazabicyclo compounds having vicinal functionality upon treatment with diamines. The keto nitrile attracts the diamine nearby to an acidic hydrogen to cause the pseudo-intramolecular imination which proceeds efficiently without any catalyst at room temperature.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Asian Journal of Chemistry

سال: 2021

ISSN: ['0970-7077', '0975-427X']

DOI: https://doi.org/10.14233/ajchem.2021.23016